One-step room-temperature solid-phase synthesis of ZnFe2O4 nanomaterials and its excellent gas-sensing property

Abstract: ZnFe2O4 nanomaterials have been synthesized by simple one-step solid-phase chemical reaction between Zn(CH3COO)2·2H2O, FeCl3·9H2O and NaOH within a very short time at room temperature. The solid-phase products were characterized by X-ray diffraction, energy-dispersive X-ray spectroscopy, thermogravimetic analysis, transmission electron microscopy and scanning electron microscopy. Results indicated that the particle size of product can be obviously let up and the agglomeration phenomenon can be improved by the surfactant. Moreover, the ZnFe2O4 nanomaterials were applied in gas sensor and exhibited much better sensing performance than bulk ZnFe2O4. The as-prepared ZnFe2O4 nanomaterials have high sensitivity, good selectivity and fast response/recovery characteristic for ethanol and hydrogen sulfide. The improved ZnFe2O4 nanomaterials have high response value of 21.5 and 14.8 for ethanol and hydrogen sulfide in the optimized operating temperature of 332°C and 240°C, respectively. The response and recovery time was found to be within 4s and 14s for ethanol, while 7s and 25s for hydrogen sulfide. [Copyright &y& Elsevier]