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Cover Picture: Development of Palladium Surface-Enriched Heteronuclear Au-Pd Nanoparticle Dehalogenation Catalysts in an Ionic Liquid (Chem. Eur. J. 4/2013).

Authors :
Yuan, Xiao
Sun, GENg
Asakura, Hiroyuki
Tanaka, Tsunehiro
ChEN, Xi
Yuan, Yuan
LaurENczy, Gabor
Kou, Yuan
Dyson, Paul J.
Yan, Ning
Source :
Chemistry - A European Journal. Jan2013, Vol. 19 Issue 4, p1137-1137. 1p.
Publication Year :
2013

Abstract

Bimetallic Au–Pd nanoparticles were prepared in the functionalized ionic liquid [C2OHmim][NTf2] by the thermal decomposition of Pd(OAc)2 and Au(OAc)3. The Au atoms are mostly located in the NP core, leaving the Pd atoms ENriched at the surface. Moreover, the Pd atoms are electropositive, which leads to high activity in catalytic dehalogENation reactions. The activity of the heteronuclear nanoparticles may be attributed to charge transfer from Pd to Au and consequENtly to more efficiENt reductive elimination. For more details, see the Full Paper by N. Yan et   al. on page   1227   ff. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
19
Issue :
4
Database :
Academic Search Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
84783532
Full Text :
https://doi.org/10.1002/chem.201390007