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Modification of Zr-doped titania nanotube arrays by urea pyrolysis for enhanced visible-light photoelectrochemical H2 generation
- Source :
-
Electrochimica Acta . Jan2013, Vol. 87, p794-800. 7p. - Publication Year :
- 2013
-
Abstract
- Abstract: Zr-doped TiO2 nanotube arrays (Zr-TiO2-NT) and TiO2 nanotube arrays (TiO2-NT) were prepared via anodic oxidation of titanium foils in ethylene glycol solution and modified by heat treatment in the presence of urea pyrolysis products at 400°C. Zr doping changes the morphology of Zr-TiO2-NT and its conduction band edge shifts negatively compared with that of TiO2-NT. For the modification of Zr-TiO2-NT in the presence of urea pyrolysis products, Zr doping can not only enhance the polymerization degree of the surface-modified carbon nitride polymers but also promote the N doping. The modified TiO2-NT and Zr-TiO2-NT films exhibit significant photocurrent responses upon visible light irradiation. Zr doping improves markedly the visible-light photoelectrochemical H2 production of the modified Zr-TiO2-NT. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 00134686
- Volume :
- 87
- Database :
- Academic Search Index
- Journal :
- Electrochimica Acta
- Publication Type :
- Academic Journal
- Accession number :
- 84765612
- Full Text :
- https://doi.org/10.1016/j.electacta.2012.09.023