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Synthesis, crystal structure, and magnetic properties of a new manganese(II) complex with nitronyl nitroxide.
- Source :
-
Russian Journal of Coordination Chemistry . Jan2013, Vol. 39 Issue 1, p130-133. 4p. - Publication Year :
- 2013
-
Abstract
- A new manganese(II) complex [MnCl(NIT-1′-MeBzIm)] · 3HO (NIT-1′-MeBzIm = 2-{2′-[(l′-methyl)benzimidazolyl]}-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) has been prepared and structurally characterized by single-crystal X-ray diffraction. The complex crystallizes in monoclinic, space group C2/ c, Z = 4. Crystal data: CHClMnNO, M = 764.52, a = 17.261(3) Å, b = 21.317(4) Å, c = 11.744(2) Å, β = 108.464(2)°. The X-ray analysis reveals that Mn(II) atom is six-coordinated with a distorted octahedral geometry. The complex was linked by intermolecular hydrogen bonds, leading to a 2D network configuration. Magnetic investigation indicates the existence of interamolecular interactions is ferromagnetic with J = 1.11 cm. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10703284
- Volume :
- 39
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Russian Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 84580572
- Full Text :
- https://doi.org/10.1134/S1070328412120020