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Stimuli-Responsive Folding and Unfolding of a Polymer Bearing Multiple Cerium(IV) Bis(porphyrinate) Joints: Mechano-imitation of the Action of a Folding Ruler.
- Source :
-
Angewandte Chemie International Edition . Jan2013, Vol. 52 Issue 1, p397-400. 4p. - Publication Year :
- 2013
-
Abstract
- A pivotal guest role: A new porphyrin polymer, poly(PorZn⋅DD) (see picture, pink/purple), composed of a porphyrinatozinc and a porphyrin double‐decker complex as a repeating unit was synthesized. In poly(PorZn⋅DD), porphyrinatozinc complexes recognize a divalent amine (tan/red) to induce an intramolecular pivoting motion through the rotation of porphyrin double‐decker complexes and the polymer undergoes shortening and compaction. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 52
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 84482617
- Full Text :
- https://doi.org/10.1002/anie.201205584