Back to Search
Start Over
Unexpected positive role of oxygen vacancies in Na-doped ZnO.
- Source :
-
Journal of Applied Physics . Dec2012, Vol. 112 Issue 11, p113510. 6p. 1 Black and White Photograph, 1 Chart, 6 Graphs. - Publication Year :
- 2012
-
Abstract
- The interaction of Na impurities and O vacancies (VO) in ZnO was studied in theory and experiment. The VO facilitated substitutional Na (NaZn/NaZn-) acceptors with inhibiting interstitial Na (Nai/Nai+) donors, which may benefit the p-type conductivity. The formed (NaZn-VO)+/0 complexes induced the change of band structures of ZnO, with the broadening of gap energies and disappearance of the VO2+-related impurity level, which confirmed by the blue shift of the near-band-edge (NBE) UV emission and the decay of the visible emission in PL spectra. The strong and dominant NBE UV emission suggested acceptable luminescence behaviors of Na-doped ZnO. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00218979
- Volume :
- 112
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Journal of Applied Physics
- Publication Type :
- Academic Journal
- Accession number :
- 84341855
- Full Text :
- https://doi.org/10.1063/1.4768279