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Poly(benzyl ether) dendrons without conventional gelation motifs as a new kind of effective organogelators.
- Source :
-
Chinese Science Bulletin . 2012, Vol. 57 Issue 33, p4289-4295. 7p. - Publication Year :
- 2012
-
Abstract
- Two poly(benzyl ether) dendrons, decorated in their periphery with nitrile groups, were divergently synthesized and fully characterized. Their gelation properties were studied by using scanning electron microscopy (SEM), X-ray crystal structure analysis and concentration- and temperature-dependent H NMR spectroscopy. It was found that the gelation capability of these dendrons was highly dependent on dendron generation, and the second-generation dendron G-CN proved to be highly efficient organogelator despite the lacking of any conventional gelation motifs, such as amides, long alkyl side chains and steroidal groups. The multiple strong π-π stacking interactions and hydrogen bonding interactions due to the peripheral isophthalonitrile motifs were proved to be the main driving forces to form the self-assembled gel. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10016538
- Volume :
- 57
- Issue :
- 33
- Database :
- Academic Search Index
- Journal :
- Chinese Science Bulletin
- Publication Type :
- Academic Journal
- Accession number :
- 83371658
- Full Text :
- https://doi.org/10.1007/s11434-012-5479-2