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Heterometallic cubane-type clusters containing group 13 and 16 elements.
- Source :
-
Pure & Applied Chemistry . Nov2012, Vol. 84 Issue 11, p2233-2241. 9p. - Publication Year :
- 2012
-
Abstract
- Heterometallic cubane-type clusters were synthesized from the reaction of group 6 and 8 metallaboranes using transition-metal carbonyl compounds. Structural and spectroscopic study revealed the existence of novel "capped-cubane" geometry. In addition, the crystal structure of these clusters distinctly confirms the presence of boride unit as one of the vertices. These clusters possess 60 cluster valence electrons (cve) and six metal--metal bonds. A plausible pathway for the formation of ruthenium-capped cubane has been described. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00334545
- Volume :
- 84
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Pure & Applied Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 82824870
- Full Text :
- https://doi.org/10.1351/PAC-CON-11-10-17