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Formation of bromocarbenium bromide ion pairs in the electrophilic bromination of highly...
- Source :
-
Journal of Organic Chemistry . 05/16/97, Vol. 62 Issue 10, p3176. 7p. 6 Diagrams, 6 Charts, 3 Graphs. - Publication Year :
- 1997
-
Abstract
- Examines an evidence for the formation of bromocarbenium bromide ion pairs in the electrophilic bromination of reactive olefins in chlorinated aprotic solvents. Measurement of the kinetic constants and activation parameters; Examination of the stability of the dibromides; Observation of the lack of anti stereospecificity in the tribromide addition.
- Subjects :
- *BROMIDE ions
*BROMINATION
*ALKENES
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 62
- Issue :
- 10
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 82575
- Full Text :
- https://doi.org/10.1021/jo9620526