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Synthesis and alkali cation extraction ability of 1,3-alt-thiacalix[4]mono(crown) ethers

Authors :
Csokai, Viktor
Grün, Alajos
Parlagh, Gyula
Bitter, István
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Oct2002, Vol. 43 Issue 42, p7627. 3p.
Publication Year :
2002

Abstract

The first representatives of 1,3-alt-thiacalix[4]mono(crown-5 and -6) ethers were synthesized by the cyclocondensation of 25,27-dialkoxythiacalix[4]arenes with tetraethylene glycol ditosylate and 1,14-diiodo-3,6,9,12-tetraoxatetradecane, respectively. The complexing abilities of ligands were determined by the alkali (Li+, Na+, K+, Rb+, Cs+) picrate extraction method. [Copyright &y& Elsevier]

Subjects

Subjects :
*CALIXARENES

Details

Language :
English
ISSN :
00404039
Volume :
43
Issue :
42
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
7883441
Full Text :
https://doi.org/10.1016/S0040-4039(02)01594-0