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Iridium(I)-catalyzed hydrogen peroxide oxidation of hydroxamic acids and hetero Diels–Alder reaction of the acyl nitroso intermediates with cyclopentadiene
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Aug2002, Vol. 43 Issue 35, p6159. 3p. - Publication Year :
- 2002
-
Abstract
- [Ir(I)(coe)2Cl]2 (2 mol%)-catalyzed hydrogen peroxide oxidation of hydroxamic acids in the presence of cyclopentadiene gave the corresponding cycloadducts up to 97% yield. With a catalyst loading of 0.05 mol%, a maximum TON was attained to 740. [Copyright &y& Elsevier]
- Subjects :
- *HYDROGEN peroxide
*OXIDATION
Subjects
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 43
- Issue :
- 35
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 7854028
- Full Text :
- https://doi.org/10.1016/S0040-4039(02)01277-7