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ChemInform Abstract: Biomimetic Catalyzed Enantioselective Decarboxylative Aldol Reaction of β-Ketoacids with Trifluoromethyl Ketones.

Authors :
Zheng, Yan
Xiong, Heng-Ying
Nie, Jing
Hua, Ming-Qing
Ma, Jun-An
Source :
ChemInform. Sep2012, Vol. 43 Issue 36, pno-no. 1p.
Publication Year :
2012

Abstract

The (DHQD)2AQN-catalyzed title reaction affords a series of trifluoromethyl-substituted tertiary alcohols (III) and (IV) in good to high yields and enantioselectivities (up to 90% e.e.). [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09317597
Volume :
43
Issue :
36
Database :
Academic Search Index
Journal :
ChemInform
Publication Type :
Academic Journal
Accession number :
78361113
Full Text :
https://doi.org/10.1002/chin.201236059