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A tris(alkyl)yttrium compound containing six β-agostic Si-H interactions.
- Source :
-
Chemical Communications . 2/14/2009, Issue 6, p656-658. 3p. - Publication Year :
- 2009
-
Abstract
- The new homoleptic rare earth compound [Y(C(SiHMe2)3)3] (2) is prepared in 82% yield by salt metathesis of YCl3 and 3 equivalents of [KC(SiHMe2)3] (1); two α-agostic Y· · ·(H-Si) interactions are observed for each C(SiHMe2)3 ligand in 2, giving six agostic interactions per yttrium(III) center. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 78075775
- Full Text :
- https://doi.org/10.1039/b818630h