Neutron diffraction study of monoclinic brannerite-type CoV2O6

Abstract: A variable-temperature powder neutron diffraction study of the monoclinic brannerite-type CoV2O6 (space group C2/m, a=9.2531(2), b=3.5040(1), c=6.6201(1) Å and β=111.617(1)° at 300K) is reported. No structural transition is observed down to 4K, but a magnetostriction accompanying antiferromagnetic order at T N =15K is discovered. Antiferromagnetic order observed below T N has an a×b×2c supercell in which Co2+ moments of magnitude 4.77(4)μB at 4K lie in the ac plane and are ferromagnetically coupled within chains of edge-sharing CoO6 octahedra parallel to b. Ferromagnetic chains are coupled antiferromagnetically to neighbouring chains in the a and c directions, and a model for the interchain order in the reported 1/3 magnetization plateau region is proposed. [Copyright &y& Elsevier]