Neutron Diffraction Study of Unusual Phase Separation in the Antiperovskite Nitride Mn3ZnN.

The antiperovskite Mn3ZnN is studied by neutron diffraction at temperatures between 50 and 295 K. Mn3ZnN crystaUizes to form a cubic structure at room temperature (Cl phase). Upon cooling, another cubic structure (C2 phase) appears at around 177 K. Interestingly, the C2 phase disappears below 140 K. The maximum mass concentration of the C2 phase is approximately 85% (at 160 K). The coexistence of C1 and C2 phase in the temperature interval of 140--177 K implies that phase separation occurs. Although the C1 and C2 phases share their composition and lattice symmetry, the C2 phase has a sUghtly larger lattice parameter (&Dgr;a ≈ 0.53%) and a different magnetic structure. The C2 phase is further investigated by neutron difeaction under high-pressure conditions (up to 270 MPa). The results shovi that the unusual appearance and disappearance of the C2 phase is accompanied by magnetic ordering. MiijZnN is thus a valuable subject for study of the magneto-lattice effect and phase separation behavior because this is rarely observed in nonoxide materials. [ABSTRACT FROM AUTHOR]