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Dinuclear arene ruthenium dichloro complexes designed for host–guest propensity
- Source :
-
Journal of Organometallic Chemistry . Sep2012, Vol. 714, p81-87. 7p. - Publication Year :
- 2012
-
Abstract
- Abstract: The synthesis and the crystal structures of several wheel-and-axle metal–organic (waamo) complexes are studied. The design of such systems is basically constituted by the binding between two Ru(II)(p-cymene)Cl2 units (wheels) and an organic spacer (axle), bearing pyridinic and/or cyano functions. Particular attention is given to the solid-state organization of the waamo complexes and to their propensity to create acceptors sites for guest species The inverted piano-stool motif, a characteristic synthon of half-sandwich ruthenium units, is always observed here, generating well defined layers of host molecules. Both polycatenated and host–guest systems were generated in order to achieve a compact packing. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 0022328X
- Volume :
- 714
- Database :
- Academic Search Index
- Journal :
- Journal of Organometallic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 77770081
- Full Text :
- https://doi.org/10.1016/j.jorganchem.2012.03.020