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Acylation of aromatic compounds using moisture insensitive InCl3 impregnated mesoporous Si-MCM-41 catalyst

Authors :
Choudhary, Vasant R.
Jana, Suman K.
Patil, Nilesh S.
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Feb2002, Vol. 43 Issue 6, p1105. 3p.
Publication Year :
2002

Abstract

Acylation of aromatic compounds (benzene, toluene, p-xylene, mesitylene, anisole, naphthalene, methylnaphthalene and methoxynaphthalene) by an acyl chloride (benzoyl chloride, phenylacetyl chloride, propionyl chloride or butyryl chloride) in high yield, in a short reaction period (3 h), even in the presence of moisture in the aromatic substrate or solvent (dichloroethane), can be accomplished at low temperature (80±1°C) using an InCl3 impregnated Si-MCM-41 catalyst in low catalyst concentration. [Copyright &y& Elsevier]

Details

Language :
English
ISSN :
00404039
Volume :
43
Issue :
6
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
7746625
Full Text :
https://doi.org/10.1016/S0040-4039(01)02335-8