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Study of the diffraction mediated selective adsorption through the close-coupling and diabatic distorted wave formalisms. Application to the 4He–Cu(110) system.
- Source :
-
Journal of Chemical Physics . 4/1/1989, Vol. 90 Issue 7, p3823. 8p. - Publication Year :
- 1989
-
Abstract
- Two different formalisms, one based on close-coupling equations and other on the distorted wave approximation, have been applied to the low energy elastic scattering of 4He atoms by a corrugated copper surface, Cu(110). Diffraction intensities and energetic positions and half-widths (selective adsorption resonances) have been obtained and compared with experimental and previous theoretical results, respectively. For this trapping process, and within the close-coupling framework, a plot of the diffraction channels (open and closed) has turned out to be very useful and a good guide in order to know the disposition of them at each interesting angular region. Also, a very accurate method, already employed successfully to treat resonances in the vibrational and/or rotational predissociation of van der Waals molecules, has been found to be also adequate here. [ABSTRACT FROM AUTHOR]
- Subjects :
- *SCATTERING (Physics)
*VAN der Waals forces
Subjects
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 90
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 7655798