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Synthesis and reactivity of dimolybdathiaborane cluster [(CpMo)BSH] (Cp = η-CMe).
- Source :
-
Journal of Chemical Sciences . Nov2011, Vol. 123 Issue 6, p847-851. 5p. 2 Diagrams, 2 Charts. - Publication Year :
- 2011
-
Abstract
- Chemistry and reactivity of dimolybdathiaborane, [(CpMo)BSH], 1, obtained from the reaction of 2-mercaptobenzothiazole, [CpMoCl] and [LiBH.thf], has been explored with dinuclear metal carbonyl [Fe(CO)]. As a result, reaction of 1 with [Fe(CO)] yielded heterometallathiaborane, [(CpMo)BHSFe(CO)], 2 in good yield. Both the new compounds have been characterized in solution by H, B and C NMR spectroscopy and the structural types were unequivocally established by X-ray crystallographic analysis of compound 2. Cluster 2 has a bicapped octahedral geometry with the {Fe(CO)} fragment occupying one of the high-connectivity cluster vertexes rather than a capping position. Interestingly, cluster 1 undergoes geometric changes (bicapped trigonal bipyramid → bicapped octahedron) on the addition of two-electron {Fe(CO)} fragment to 1. [Figure not available: see fulltext.] [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09743626
- Volume :
- 123
- Issue :
- 6
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Sciences
- Publication Type :
- Academic Journal
- Accession number :
- 76515505
- Full Text :
- https://doi.org/10.1007/s12039-011-0175-3