Interoscillator coupling effects on the OH stretching band of liquid water.

We have studied the OH stretch spectrum in water to explore the effects of interoscillator coupling. Both H2O, which may have significant intra and intermolecular coupling, and dilute HOD in D2O, which is isotopically decoupled, were studied over a broad range of temperature from -33 °C to 160 °C. By adding a small amount of a calibration dopant, we obtained quantitative spectra. We found interoscillator coupling plays a large role at all temperatures. At high temperature, intramolecular coupling contributes to a downshift in the peak position for H2O as compared to HOD. Intermolecular coupling, however, still has some influence at high temperature. At low temperature, the large excess intensity below 3200 cm-1 in H2O compared to HOD we find is due to an enhanced Raman cross section due to intermolecularly coupled in-phase OH stretch oscillations. We define a degree of delocalization for coupling as the idealized number of perfectly in-phase oscillators that could cause the enhanced scattering and find N[bar_over_tilde:_approx._equal_to]2 for liquid H2O at -33 °C. An exact isosbestic crossing is not found and this can be understood given the changing line shape that the intermolecular coupling can induce. All the properties of the spectrum approach those found in amorphous solid water or ice near the supercooled water anomalous temperature, Ts[bar_over_tilde:_approx._equal_to]-45 °C. [ABSTRACT FROM AUTHOR]