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Three-photon resonance-enhanced ionization spectroscopy of CO(A 1Π←X 1Σ+). II. Line shift/profile and the ac Stark effect.
- Source :
-
Journal of Chemical Physics . 2/1/1994, Vol. 100 Issue 3, p1866. 8p. - Publication Year :
- 1994
-
Abstract
- The influence of the ac Stark effect on the line shift and line shape is studied in the three-photon resonance enhanced ionization spectroscopy of COA 1Π(v’)←X 1Σ(v‘=0), where v’=1, 2, or 3. Experimental results show that the line shift varies from one vibrational band to another and differs for various lines in the same band, although it is to a lesser degree. This is given an adequate theoretical elucidation. A detailed calculation, based on the ac stark effect with evaluation of the dipole matrix element, gives -0.66, -0.31, and 0.87 cm-1 for P11 of the (1-0), (2-0), and (3-0) band, respectively, where the negative values stand for red shift while the positive one for blue shift. These results are very close to the experimental observations, viz., -0.48, -0.13, and 0.77 for P11 of the (1-0), (2-0), and (3-0) bands, respectively. Furthermore, the line shape is found to be asymmetrically broadened. For the blue-shift line, the red side is much steeper than the blue side, whereas for the red-shift line, the reverse situation appears. This is again explained as due to the ac Stark effect coupled with the spatial inhomogeneity of the laser field. According to this model, a numerical calculation for the line shape is provided which gives fairly good agreement with the experimental observation. [ABSTRACT FROM AUTHOR]
- Subjects :
- *PHOTONS
*RESONANCE ionization spectroscopy
*CARBON monoxide
*STARK effect
Subjects
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 100
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 7610620
- Full Text :
- https://doi.org/10.1063/1.466538