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Energy transfer in silver-doped rare gas matrices.
- Source :
-
Journal of Chemical Physics . 8/1/1989, Vol. 91 Issue 3, p1417. 6p. - Publication Year :
- 1989
-
Abstract
- The energy transfer between Ag atoms and dimers isolated in rare gas matrices has been studied by time-resolved fluorescence spectroscopy. In the presence of dimers, excitation of the atomic 5s→5p transitions produces not only the emission bands of the Ag atom, but also those of the Ag dimer. This process has been investigated and the mechanism identified as a Förster–Dexter-type energy transfer from silver atoms (donor) to dimers (acceptor). Rise and decay curves of the emissions from atoms and dimers have been analyzed in a concentration dependence study and a critical radius for the energy transfer of 39±5 Å was derived. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ENERGY transfer
*DIMERS
Subjects
Details
- Language :
- English
- ISSN :
- 00219606
- Volume :
- 91
- Issue :
- 3
- Database :
- Academic Search Index
- Journal :
- Journal of Chemical Physics
- Publication Type :
- Academic Journal
- Accession number :
- 7608907
- Full Text :
- https://doi.org/10.1063/1.457101