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( Z)-Selective Partial Hydrogenation of Internal Alkynes by Using Palladium Nanoparticles Supported on Nitrogen-Doped Carbon Nanofiber.

Authors :
Lee, Youngjin
Motoyama, Yukihiro
Tsuji, Keita
Yoon, Seong-Ho
Mochida, Isao
Nagashima, Hideo
Source :
ChemCatChem. Jun2012, Vol. 4 Issue 6, p778-781. 4p.
Publication Year :
2012

Abstract

The article discusses a study which synthesized palladium nanoparticles supported on nitrogen-doped carbon nanofiber (N-CNF-H) by thermally decomposing Pd2(dba)3CHCl3 in the presence of N-CNF-H. The study found that the Pd/N-CNF-H compounds act as efficient catalysts in the partial hydrogenation of internal alkynes to the corresponding (Z)-alkenes. It also suggested the significance of N-CNF-H in the preparation of heterogenous poisoning catalysts.

Details

Language :
English
ISSN :
18673880
Volume :
4
Issue :
6
Database :
Academic Search Index
Journal :
ChemCatChem
Publication Type :
Academic Journal
Accession number :
75913854
Full Text :
https://doi.org/10.1002/cctc.201200058