Microstructure and photoluminescent properties of Sr2SiO4:Eu3+ phosphors with various NH4Cl flux concentrations

Abstract: In this paper, effect of NH4Cl flux concentrations (0, 1, 2, 3 and 4wt%) on the crystal structure, morphology and photoluminescent properties of Sr2SiO4:Eu3+ phosphors synthesized by a microwave sintering at 1200°C for 1h was investigated and discussed. X-ray powder diffraction analysis showed the crystal structure was not affected and the pure Sr2SiO4 phase was formed without second phase or phases of starting materials when adding with the NH4Cl flux. The SEM images indicated that increase of the NH4Cl flux enlarged the particle size of the phosphor particles. The photo-luminescence results showed the addition of 1wt% NH4Cl flux much improved the emission intensity at λ em of 617nm as the excitation spectrum at λ ex of 395nm. The decay times of Sr2SiO4:Eu3+ phosphors with different NH4Cl flux concentrations were obtained around 2.47–2.52ms. [Copyright &y& Elsevier]