EDTA-mediated shape-selective synthesis of Bi2WO6hierarchical self-assemblies with high visible-light-driven photocatalytic activitiesElectronic supplementary information (ESI) available. See DOI: 10.1039/c1ce05671a.

Bi2WO6with multilayered disc-like and 3D hierarchical nest-like architectures self-assembled from 2D nanosheets were successfully synthesized by a hydrothermal method in EDTA-mediated processes. It was found that the morphology modulation of the as-obtained products could be easily realized simply by changing the amount of EDTA introduced into the reaction system. The stepwise self-assembly formation mechanisms for two different hierarchical architectures were proposed on the basis of a series of time-dependent experiments. The photocatalytic activities of the different Bi2WO6samples for the degradation of Rhodamine B (RhB) were also evaluated. Due to the unique morphology, porous structure and large surface area, Bi2WO6nest-like architectures exhibited better activity performance than Bi2WO6multilayered microdiscs. The present work not only presents an efficient way for the selectively controllable preparation of Bi2WO6hierarchical structures viaself-assembly from 2D nanosheets, but also provides a step forward in the design of photocatalysts with controllable morphology and enhanced photocatalytic activities. [ABSTRACT FROM AUTHOR]