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Synthesis, Characterization, and Crystal Structure of a New Cu Complex with Salen-Type Ligand.
- Source :
-
Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry . Sep2011, Vol. 41 Issue 8, p973-978. 6p. - Publication Year :
- 2011
-
Abstract
- A new dinuclear CuII complex, [Cu2(3-MeOSalamo-2)(H2O)3]·2pic·CH3COCH3·H2O, has been synthesized by the reaction of copper(II) picrate tetrahydrate with H2(3-MeOSalamo-n) (n = 2). X-ray crystallographic analysis reveals that the complex is a dinuclear structure when the O-alkyl chain length is relatively short (two CH2 groups), while a tetranuclear structure is obtained when the O-alkyl chain length becomes longer (four CH2 groups). In the complex, the μ-phenoxo bridging, picratol, and intermolecular hydrogen bonds play important roles in assembling CuII ions and ligands. Interestingly, the complex not only has a helical chain, but has an infinite metal–water chain supramolecular structure. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 15533174
- Volume :
- 41
- Issue :
- 8
- Database :
- Academic Search Index
- Journal :
- Synthesis & Reactivity in Inorganic, Metal-Organic, & Nano-Metal Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 66285608
- Full Text :
- https://doi.org/10.1080/15533174.2011.591329