Switching of excited states in cyclometalated platinum complexes incorporating pyridyl-acetylide ligands (Pt–CC–py): a combined experimental and theoretical studyThis paper is dedicated to Professor Didier Astruc on the occasion of his 65th birthday.Electronic supplementary information (ESI) available: ESI1—experimental details and computational details, TD-DFT results; ESI2—MO diagrams. See DOI: 10.1039/c1nj20225a

This article presents the design of cyclometalated platinum(ii) complexes incorporating pyridyl-appended acetylide ligands of the form Pt–CC–py, acting either as sites for protonation or methylation reactions or as a host receptor for binding metal cations. The complexes studied are Pt(t-Bu2phbpy)(–CC–py), 2, which can undergo protonation at the pyridyl N; its cationic N-methylated derivative [Pt(t-Bu2phbpy)(–CC–pyMe)]+, 4, which serves as a model of the N-protonated species; and a derivative in which the pyridyl ring is incorporated into a macrocyclic diamide-crown ether ligand (3). The co-ligand t-Bu2phbpy is a cyclometalated, NNC-coordinated phenylbipyridine ligand carrying tert-butyl groups at the 4-positions of the pyridyl rings. The photophysical properties of the neutral compounds 2and 3have been compared to those of the pyridinium, methyl-pyridinium or metal-complexed species (namely 2-H+, 4and 3-Pb2+). Detailed TD-DFT calculations provide a theoretical basis to account for the experimentally-observed changes upon protonation/methylation/complexation. The joint TD-DFT and experimental studies provide evidence for an unprecedented molecular switch in the nature of the excited state (from mixed L′LCT/MLCT to ML′CT) in which the acceptor ligand in the CT process switches from being the NNC ligand to the pyridyl acetylide. [ABSTRACT FROM AUTHOR]