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Unexpected Formation of (E)-4-Alkene 1,3-Diketones from the Three-Component Reaction of Lithium Selenolates with 1-(1-Alkynyl)cyclopropyl Ketones and Aldehydes.
- Source :
-
Journal of Organic Chemistry . 7/15/2011, Vol. 76 Issue 14, p5598-5605. 4p. - Publication Year :
- 2011
-
Abstract
- A novel three-component stereoselective synthesis of (E)-4-alkene 1,3-diketones from lithium selenolates, 1-(1-alkynyl)cyclopropyl ketones, and aldehydes is reported. This reaction afforded the products in moderate to good yields with the formation of a new C-Se single bond, a new C-C double bond, and a new C-O double bond. [ABSTRACT FROM AUTHOR]
- Subjects :
- *ALKENES
*KETONES
*LITHIUM
*CHEMICAL bonds
*ALDEHYDES
Subjects
Details
- Language :
- English
- ISSN :
- 00223263
- Volume :
- 76
- Issue :
- 14
- Database :
- Academic Search Index
- Journal :
- Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 65179317
- Full Text :
- https://doi.org/10.1021/jo2005439