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The use of a multi-method approach to identify the pigments in the 12th century manuscript Liber Floridus
- Source :
-
Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy . Oct2011, Vol. 80 Issue 1, p125-132. 8p. - Publication Year :
- 2011
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Abstract
- Abstract: A selection of illuminations of the 12th century manuscript Liber Floridus was analysed with Raman spectroscopy (in situ and laboratory measurements), X-ray fluorescence spectroscopy, UV-fluorescence photography and infrared reflectography (IRR). The aim of this study is to determine the pigments used, in order to search for anachronisms. Using a combination of Raman spectroscopy (molecular information) and X-ray fluorescence spectroscopy (elemental information) following pigments could be identified: ultramarine (Na8–10Al6Si6O24S2–4), azurite (2CuCO3·Cu(OH)2), caput mortuum (Fe2O3), vermilion (HgS), orpiment (As2S3) and lead white (2PbCO3·Pb(OH)2). Moreover, two synthetic red pigments, PR4 and PR176, and a degradation product, gypsum (CaSO4·2H2O), were present in the manuscript. To establish the origin of the modern materials UV-fluorescence photography was used. Infrared reflectography (IRR) was applied to visualise the underdrawing of the investigated folios. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13861425
- Volume :
- 80
- Issue :
- 1
- Database :
- Academic Search Index
- Journal :
- Spectrochimica Acta Part A: Molecular & Biomolecular Spectroscopy
- Publication Type :
- Academic Journal
- Accession number :
- 64859292
- Full Text :
- https://doi.org/10.1016/j.saa.2011.03.005