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Asymmetric heterobimetallic mixed-valence complex trans-[(SO3)Co(cyclam)(NCS)Ru(NH3)4(NCS)](BF4): Synthesis and characterization
- Source :
-
Polyhedron . Aug2011, Vol. 30 Issue 12, p2083-2089. 7p. - Publication Year :
- 2011
-
Abstract
- Abstract: [(SO3)Co(cyclam)(NCS)] and [(SO3)Co(cyclam)-NCS-Ru(NH3)4(NCS)](BF4) complexes were synthesized and characterized by means of X-ray diffraction, electrochemistry, elemental analysis, and spectroscopic techniques. Crystallographic and FTIR data indicated NCS− ligand is coordinated to Co through the nitrogen atom in the monomer species. Electrochemistry and FTIR data of the material isolated after reductive electrolysis of [(SO3)Co(cyclam)(NCS)] hint that NCS− and SO3 2− are released thus forming [Co(cyclam)(L)2]2+, where L is solvent molecules. The formation of the heterobimetallic mixed-valence complex induced a thermodynamic stabilization of Co and Ru metal atoms in the oxidized and reduced states, respectively. According to the Robin and Day classification, a Class II system with a comproportionation constant of 5.78×106 is suggested for the mixed-valence complex based on the electrochemical and UV–Vis–NIR results. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 02775387
- Volume :
- 30
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Polyhedron
- Publication Type :
- Academic Journal
- Accession number :
- 62846170
- Full Text :
- https://doi.org/10.1016/j.poly.2011.05.019