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A Concise, Stereocontrolled Total Synthesis of Rippertenol.
- Source :
-
Journal of the American Chemical Society . 6/15/2011, Vol. 133 Issue 23, p8850-8853. 4p. - Publication Year :
- 2011
-
Abstract
- The first total synthesis of the unique terpene rippertenol, a molecule with dense stereochemical complexity arrayed on a compact framework largely devoid of functional groups, is described. Key elements include orchestrated and unique applications of aldol condensations, Diels-Alder chemistry, and a ring expansion to advance a chiral starting material containing a single chiral center into the final target in a concise and diastereocontrolled manner. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 133
- Issue :
- 23
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 61964393
- Full Text :
- https://doi.org/10.1021/ja202859f