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Ruthenium-Catalyzed Hydrovinylation of N-Acetylenamines Leading to Amines with a Quaternary Carbon Center.

Ruthenium-Catalyzed Hydrovinylation of N-Acetylenamines Leading to Amines with a Quaternary Carbon Center.

Authors :
Qiu-Shi Wang
Jian-Hua Xie
Wei Li
Shou-Fei Zhu
Li-Xin Wang
Qi-Lin Zhou
Source :
Organic Letters. Jul2011, Vol. 13 Issue 13, p3388-3391. 4p.
Publication Year :
2011

Abstract

A catalytic hydrovinylation of N-acetylenamines with ethylene is reported. This new hydrovinylation reaction is catalyzed by a ruthenium hydride complex, RuHCl(CO)(PCy3)2, providing a series of N-acetylamines with a quaternary carbon center with up to 99% yield. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15237060
Volume :
13
Issue :
13
Database :
Academic Search Index
Journal :
Organic Letters
Publication Type :
Academic Journal
Accession number :
61949640
Full Text :
https://doi.org/10.1021/ol201142v