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Ruthenium-Catalyzed Hydrovinylation of N-Acetylenamines Leading to Amines with a Quaternary Carbon Center.
Ruthenium-Catalyzed Hydrovinylation of N-Acetylenamines Leading to Amines with a Quaternary Carbon Center.
- Source :
-
Organic Letters . Jul2011, Vol. 13 Issue 13, p3388-3391. 4p. - Publication Year :
- 2011
-
Abstract
- A catalytic hydrovinylation of N-acetylenamines with ethylene is reported. This new hydrovinylation reaction is catalyzed by a ruthenium hydride complex, RuHCl(CO)(PCy3)2, providing a series of N-acetylamines with a quaternary carbon center with up to 99% yield. [ABSTRACT FROM AUTHOR]
- Subjects :
- *RUTHENIUM compounds
*CATALYSIS
*ETHYLENE
*CHEMICAL reactions
*ENAMINES
*AMINES
Subjects
Details
- Language :
- English
- ISSN :
- 15237060
- Volume :
- 13
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Organic Letters
- Publication Type :
- Academic Journal
- Accession number :
- 61949640
- Full Text :
- https://doi.org/10.1021/ol201142v