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Scaffolding, Ladders, Chains, and Rare Ferrimagnetism in Intermetallic Borides: Electronic Structure Calculations and Magnetic Ordering.
- Source :
-
Journal of the American Chemical Society . 5/4/2011, Vol. 133 Issue 17, p6832-6840. 9p. - Publication Year :
- 2011
-
Abstract
- The electronic structures of "Ti9-nFe2+nRu18B8" (n= 0, 0.5, 1, 2, 3); in connection to the recently synthesized Ti9-nFe2+n-RU18B8(n = 1, 2), have been investigated and analyzed using LSDA tight-binding calculations to elucidate the distribution of Fe and Ti, to determine the maximum Fe content, and to explore possible magnetic structures to interpret experimental magnetization results. Tbrough a combination of calculations on specific models and using tbe rigid band approximation, which is validated by the DOS curves for "T9-nFe2+nRu18B8" (n = 0, 0.5, 1, 2,3), mixing of Fe and Ti is anticipated at both tbe 2b- and 4h-chain sites. The model "Ti8.5Fe2.5Ru18B8" (n = 0.5) revealed that both Brewer-type Ti-Ru interactions as well as ligand field splitting ofthe Fe 3d orbitals regulated the observed valence electron counts between 220 and 228 electrons/formula unit. Finally, models of magnetic structures were created using "Ti6Fe5Ru18B8" (n = 3). A rigid band analysis of tbe LSDA DOS curves concluded preferred ferromagnetic ordering at low Fe content (n ⩽ 0.75) and ferrimagnetic ordering at higher Fe content (n > 0.75). Ferrimagnetism arises from antiferromagnetic exchange coupling in the scaffold of Fel-ladder and 4h-chain sites. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 133
- Issue :
- 17
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 61926907
- Full Text :
- https://doi.org/10.1021/ja200909r