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Sol-gel synthesis of yellow-emitting La4Ca(SiO4)3O:Ce3+ phosphors for white-light emitting diodes
- Source :
-
Materials Letters . Jul2011, Vol. 65 Issue 13, p2019-2021. 3p. - Publication Year :
- 2011
-
Abstract
- Abstract: Ce3+ doped La4Ca(SiO4)3O phosphors with silicate oxyapatite structure were synthesized by the sol-gel process. The X-ray diffraction (XRD) patterns showed that a pure phase was formed when sintering temperature was higher than 1300°C. The optical properties of La4Ca(SiO4)3O:Ce3+ phosphors with varying sintering temperature and concentration were investigated by examining their excitation and emission spectroscopy. The phosphors exhibited a broad emission band centered at 550nm which could be attributed to the 5d-4f transition of Ce3+ and a stronger excitation peak around 467nm as well as several shoulder bands, nicely matching with the widely applied blue LED chips. Higher emission intensity was observed when firing temperature above 1300°C, due to increasing crystallinity of the powders. When Ce3+ concentration was equal to 5 at%, the sample exhibited the optimum excitation and emission efficiency. The results indicate that La4Ca(SiO4)3O:Ce3+ is a promising candidate in the application of blue chip excited white light emitting diodes (LEDs). [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 0167577X
- Volume :
- 65
- Issue :
- 13
- Database :
- Academic Search Index
- Journal :
- Materials Letters
- Publication Type :
- Academic Journal
- Accession number :
- 60786450
- Full Text :
- https://doi.org/10.1016/j.matlet.2011.04.026