Landau theory description of observed isotropic to anisotropic phase transition in mixed clay gels.

A characteristic new cooperative dehydration transition, in 1:1 Laponite-MMT cogel, was observed at Tc ≈ 60 °C, a temperature at which the storage modulus (G′) and depolarization ratio (Dp) showed sharp increase, and the isotropic cogel turned into an anisotropic one. The dehydration dynamics could be described through power-law relations: G′ ∼ (Tc - T)-γ and Dp ∼ (Tc - T)-β with γ ≈ β = 0.40 ± 0.05. The x-ray diffraction data revealed that the crystallite size decreased from 17 nm (at 20 °C) to 10 nm (at 80 °C) implying loss of free and inter-planar water. When this cogel was spontaneously cooled below Tc, it exhibited much larger storage modulii values which implied the existence of several metastable states in this system. This phase transition could be modeled through Landau theory, where the depolarization ratio was used as experimental order parameter (ψ). This parameter was found to scale with temperature, as ψ ∼ (Tc - T)-α, with power-law exponent α = 0.40 ± 0.05; interestingly, we found α ≈ β ≈ γ. [ABSTRACT FROM AUTHOR]