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Reactions of positive ions with ClN3 at 300K
- Source :
-
International Journal of Mass Spectrometry . Jun2011, Vol. 303 Issue 2/3, p220-224. 5p. - Publication Year :
- 2011
-
Abstract
- Abstract: The kinetics of eighteen positive ions with chlorine azide (ClN3) have been studied using a selected ion flow tube (SIFT). These measurements allowed for the estimation of both the ionization energy, >930kJmol−1 (>9.6eV), and the proton affinity, 713±41kJmol−1, of chlorine azide. Reaction rate constants have been determined. Product ions have been identified, and quantified when synthetic complications allowed. In addition, general reaction trends have been observed. A reaction coordinate diagram for the novel reaction of N+ with ClN3 is discussed. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 13873806
- Volume :
- 303
- Issue :
- 2/3
- Database :
- Academic Search Index
- Journal :
- International Journal of Mass Spectrometry
- Publication Type :
- Academic Journal
- Accession number :
- 60665978
- Full Text :
- https://doi.org/10.1016/j.ijms.2011.02.004