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Five three/two-fold interpenetrating architectures from self-assembly of fluorene-2,7-dicarboxylic acid derivatives and d10metalsElectronic supplementary information (ESI) available. CCDC reference numbers 803528–803531, 806385. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c0ce00662a
- Source :
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CrystEngComm . Apr2011, Vol. 13 Issue 7, p2935-2941. 7p. - Publication Year :
- 2011
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Abstract
- Five new three/two-fold interpenetrated coordination polymers, namely, [Cd(mfda)(L1)] (1), [Cd(efda)(L1)] (2), [Zn2(mfda)2(L2)]·DMF·H2O (3), [Zn2(efda)2(L2)]·(DMF)0.25, (4) and [Cd2(mfda)2(L2)2]·DMF·H2O (5) (H2mfda = 9,9-dimethylfluorene-2,7-dicarboxylic acid, H2efda = 9,9-diethylfluorene-2,7-dicarboxylic acid, L1= Methylene bis(3,5-dimethylpyrazole) and L2= 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene), have been synthesized under solvent-thermal conditions with mixed ligands. Compounds 1and 2are isostructural and possess two-dimensional (6, 3) layered structures containing two kinds of rings. Three equivalent (6, 3) net interpenetrate in a parallel fashion to form an unprecedented mat-like 2D sheet. Compounds 3and 4are almost identical in structure and display threefold interpenetrating α–Po net structures. Compound 5displays a twofold interpenetrated 3D 6-connected net with α–Po topology. The luminescent properties of these compounds have been studied in the solid state at room temperature. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14668033
- Volume :
- 13
- Issue :
- 7
- Database :
- Academic Search Index
- Journal :
- CrystEngComm
- Publication Type :
- Academic Journal
- Accession number :
- 59688882
- Full Text :
- https://doi.org/10.1039/c0ce00662a