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Control of metal-directed self-assembly by metal–amine interactionsElectronic supplementary information (ESI) available. See DOI: 10.1039/c0dt01056a.
- Source :
-
Dalton Transactions: An International Journal of Inorganic Chemistry . Mar2011, Vol. 40 Issue 12, p2778-2786. 9p. - Publication Year :
- 2011
-
Abstract
- The complexation of a tweezers ligand with zinc perchlorate in the absence and presence of amines in methanol solution was explored. L2Zn2(ClO4)4was a thermodynamic product of the reaction in the absence of an amine. The complex was shown to interact with aliphatic amines resulting in the formation of a Zn–N(amine) bond. If metal–ligand complexation was carried out in the presence of an amine the formation of a trinuclear zinc complex L3Zn36+was observed. Moreover the transformation of complex L2Zn24+to L3Zn36+occurred, when the former was subjected to an amine in the amount, which is sufficient to coordinate more than one amino group on each zinc atom. Complexes ligand-zinc-amine were shown to be kinetically stable, and the method of their preparation was crucial to the purity of the final complexes. L3Zn36+was favored under kinetic control: reagent concentration 10−5M, slow addition of zinc perchlorate to the mixture of an amine and the ligand. Under thermodynamic control (fast mixing of reagents, concentration 10−2–10−3M) formation of a mixture of complexes was observed. All pure complexes and their mixtures were characterized using UV-Vis, ROESY, PFGSE NMR and ESI-MS techniques. On the basis of DFT calculations the mechanism of influence of an amine on self-assembly was suggested. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 40
- Issue :
- 12
- Database :
- Academic Search Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 59332305
- Full Text :
- https://doi.org/10.1039/c0dt01056a