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In-plane electrophoresis in nonpolar liquids: Measurements and simulations
- Source :
-
Colloids & Surfaces A: Physicochemical & Engineering Aspects . Feb2011, Vol. 376 Issue 1-3, p89-96. 8p. - Publication Year :
- 2011
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Abstract
- Abstract: In this paper we describe electrophoresis of charged particles in a thin layer of a nonpolar liquid between two insulating substrates because this configuration is common in recently developed in-plane electronic paper. In the in-plane electrophoresis experiments a model system of charged inverse micelles in dodecane has been used which is well understood from studies of out-of-plane electrophoresis. The transient current due to drift and diffusion of charged inverse micelles is measured in thin in-plane devices upon application of a voltage step. For the modelling of the transient dynamics of charged inverse micelles without chemical reactions or convection a 1-dimensional approximation of the Poisson–Nernst–Planck (PNP) equations is developed. This approximation is valid for a sufficiently thin in-plane device and allows much faster calculations. Firstly, it is verified in the case of a sufficiently thin in-plane device and high applied voltage that the 1-dimensional approximation is in good agreement with the solution of the full 2-dimensional PNP equations with finite elements implementation. Then, the 1-dimensional approximation is used to study the transient current and trajectories of trace amounts of charged colloidal particles in different regimes depending on the screening of the electric field. Also a comparison is made to the well-studied case of out-of-plane electrophoresis. Finally, it is verified that for voltages much larger than the thermal voltage the experimental results are in good agreement with the 1-dimensional approximation, indicating that the charge transport dynamics of charged inverse micelles in the bulk are described well by the model. [Copyright &y& Elsevier]
Details
- Language :
- English
- ISSN :
- 09277757
- Volume :
- 376
- Issue :
- 1-3
- Database :
- Academic Search Index
- Journal :
- Colloids & Surfaces A: Physicochemical & Engineering Aspects
- Publication Type :
- Academic Journal
- Accession number :
- 58096132
- Full Text :
- https://doi.org/10.1016/j.colsurfa.2010.08.018