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Photoisomerization in an analogous set of ruthenium sulfoxide complexes
- Source :
-
Journal of Photochemistry & Photobiology A: Chemistry . Jan2011, Vol. 217 Issue 2/3, p341-346. 6p. - Publication Year :
- 2011
-
Abstract
- Abstract: Complexes of the type [Ru(bpy)2(OSOBnR)](PF6) where bpy is 2,2′-bipyridine and OSOBnR is a 4-substituted benzylsulfinylbenzoate with R=NO2, F, Cl, H, CH3, CF3 and OCH3, have been prepared and investigated by 1H NMR spectroscopy, cyclic voltammetry and UV–vis spectroscopy. Despite the distance of the R group from ruthenium, the Ru3+/2+ reduction potential and charge transfer absorption maximum vary predictably with the electron withdrawing nature of the group. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10106030
- Volume :
- 217
- Issue :
- 2/3
- Database :
- Academic Search Index
- Journal :
- Journal of Photochemistry & Photobiology A: Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 57516589
- Full Text :
- https://doi.org/10.1016/j.jphotochem.2010.11.002