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Chromatography in a Single Metal–Organic Framework (MOF) Crystal.
- Source :
-
Journal of the American Chemical Society . 11/24/2010, Vol. 132 Issue 46, p16358-16361. 4p. - Publication Year :
- 2010
-
Abstract
- Millimeter-sized single MOF-5 crystals are used as "chromatographic columns" to effectively separate mixtures of organic dyes. Remarkably, owing to the nanoscopic pore dimensions and the molecular-level interactions between the migrating molecules and the MOF scaffold, the separations occur over a distance of only a few hundred micrometers which is unambiguously confirmed by fluorescence confocal microscopy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00027863
- Volume :
- 132
- Issue :
- 46
- Database :
- Academic Search Index
- Journal :
- Journal of the American Chemical Society
- Publication Type :
- Academic Journal
- Accession number :
- 55570668
- Full Text :
- https://doi.org/10.1021/ja1074322