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Conversional studies towards taxoids from C19-diterpenoid alkaloids by the BAC sequence.
- Source :
-
Journal of Asian Natural Products Research . Nov2010, Vol. 12 Issue 11, p968-977. 10p. 3 Diagrams, 2 Charts. - Publication Year :
- 2010
-
Abstract
- The conversional synthesis of taxoids by the BAC sequence from the C19-diterpenoid alkaloids, 14-acetyltalatisamine (1), yunaconitine (12), and 14-acetylchasmanine (19), was designed and explored. Two aconane-type diterpenes 17 and 28, the advanced intermediates for our conversional synthesis, were synthesized. The key steps include the rupture of the C(7)-C(17) bond, the formation of imine, and the denitrogenation. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10286020
- Volume :
- 12
- Issue :
- 11
- Database :
- Academic Search Index
- Journal :
- Journal of Asian Natural Products Research
- Publication Type :
- Academic Journal
- Accession number :
- 55116131
- Full Text :
- https://doi.org/10.1080/10286020.2010.510796