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Stereoselective total synthesis of achaetolide and reconfirmation of its absolute configuration
Stereoselective total synthesis of achaetolide and reconfirmation of its absolute configuration
- Source :
-
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry . Nov2010, Vol. 51 Issue 47, p6174-6176. 3p. - Publication Year :
- 2010
-
Abstract
- Abstract: The stereoselective total synthesis of achaetolide 1 has been achieved and its absolute stereochemistry has been reconfirmed to be 3S,6R,7S,9R configuration. Keck allylation, Sharpless asymmetric dihydroxylation, and ring closing metathesis are the key steps involved in the target synthesis. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00404039
- Volume :
- 51
- Issue :
- 47
- Database :
- Academic Search Index
- Journal :
- Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 54606041
- Full Text :
- https://doi.org/10.1016/j.tetlet.2010.09.070