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Stereoselective total synthesis of achaetolide and reconfirmation of its absolute configuration

Stereoselective total synthesis of achaetolide and reconfirmation of its absolute configuration

Authors :
Srihari, P.
Kumaraswamy, B.
Shankar, P.
Ravishashidhar, V.
Yadav, J.S.
Source :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry. Nov2010, Vol. 51 Issue 47, p6174-6176. 3p.
Publication Year :
2010

Abstract

Abstract: The stereoselective total synthesis of achaetolide 1 has been achieved and its absolute stereochemistry has been reconfirmed to be 3S,6R,7S,9R configuration. Keck allylation, Sharpless asymmetric dihydroxylation, and ring closing metathesis are the key steps involved in the target synthesis. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00404039
Volume :
51
Issue :
47
Database :
Academic Search Index
Journal :
Tetrahedron Letters: International Organ for the Rapid Publication of Preliminary Communications in Organic Chemistry
Publication Type :
Academic Journal
Accession number :
54606041
Full Text :
https://doi.org/10.1016/j.tetlet.2010.09.070