Hydrothermal synthesis and magnetic properties of gadolinium-doped CoFe2O4 nanoparticles

Abstract: CoFe2−x Gd x O4 (x=0–0.25) nanoparticles were synthesized via a simple hydrothermal process at 200°C for 16h without the assistance of surfactant. The as-synthesized powders were characterized by X-ray diffraction, transmission electron microscopy, and a vibrating sample magnetometer. The X-ray diffraction results showed that the as-synthesized powders were in the pure phase with a doping amount of ≤0.25, and the peaks could be readily indexed to the cubic spinel cobalt ferrite. Transmission electron microscopy and high resolution transmission electron microscopy observations revealed that the gadolinium-doped cobalt ferrite nanoparticles were single crystal, roughly spherical, uniformly distributed, and not highly agglomerated. The room temperature magnetic field versus magnetization measurements confirmed a strong influence of gadolinium doping on the saturation magnetization and coercivity due to large lattice distortion and grain growth of small particles. [ABSTRACT FROM AUTHOR]