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A Causal Analysis on the Formation of By-products in Tannin Extract Desulfurization-Kinetics and Mechanism Research on HS- with Oxygen.

Authors :
Niu, Y. X.
Ling, K. C.
Men, X. Q.
Shen, J.
Source :
Energy Sources Part A: Recovery, Utilization & Environmental Effects. 2011, Vol. 33 Issue 1, p1-11. 11p. 1 Chart, 3 Graphs.
Publication Year :
2011

Abstract

To investigate the formation reason of by-products in tannin extract desulfurization, the kinetics of the chemical oxidation of aqueous HS- solutions have been studied in a continuous bubbling reactor. The results show that the reaction rate increased as the initial concentration of HS- increased, and the air velocity accelerated, and reaction temperature rose. The rate equation is -[image omitted] = 1.13 exp(-25622.71/RT)CHS-. By theoretical analysis and experimental research, it is discovered that the oxidation products of HS- are mainly S2O32- and not sulfur. In addition, some suggestions were put forward to reduce by-products. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
15567036
Volume :
33
Issue :
1
Database :
Academic Search Index
Journal :
Energy Sources Part A: Recovery, Utilization & Environmental Effects
Publication Type :
Academic Journal
Accession number :
54166239
Full Text :
https://doi.org/10.1080/15567031003699517