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Total Synthesis of Cryptoacetalide.

Authors :
Yan Zou
Deiters, Alexander
Source :
Journal of Organic Chemistry. 8/6/2010, Vol. 75 Issue 15, p5355-5358. 4p.
Publication Year :
2010

Abstract

We are reporting the first total synthesis of the tetracyclic terpene natural product cryptoacetalide. Key steps of the synthesis are a microwave-mediated [2+2+2] cyclotrimerization reaction to construct the central benzcne ring, and a light-mediated radical cyclization to assemble the spiro-ketal moiety. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00223263
Volume :
75
Issue :
15
Database :
Academic Search Index
Journal :
Journal of Organic Chemistry
Publication Type :
Academic Journal
Accession number :
52958373
Full Text :
https://doi.org/10.1021/jo100867v