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Chlorine isotope evidence for the anthropogenic origin of tris-(4-chlorophenyl)methane
- Source :
-
Applied Geochemistry . Sep2010, Vol. 25 Issue 9, p1301-1306. 6p. - Publication Year :
- 2010
-
Abstract
- Abstract: Compound-specific Cl-isotope analysis was performed on the persistent and bioaccumulating compound tris-(4-chlorophenyl)methane (4,4′,4″-TCPMe, referred to as TCPMe in this study) to elucidate whether its main source is natural or anthropogenic. Blubber from the Baltic grey seal (Halichoerus grypus) was extracted by continuous acetonitrile partitioning, and the TCPMe was isolated from the extract by preparative-capillary gas chromatography. Chlorine isotope analysis was subsequently performed by sealed-tube combustion in conjunction with thermal-ionization mass spectrometry (TIMS). The δ 37Cl of TCPMe was −3.5±0.5‰, similar to the previously reported δ 37Cl of technical grade p,p′-DDT (referred to as DDT in this study). The data is not consistent with a putative marine natural source of TCPMe, as enzymatic (biotic) production is reported to give values of δ 37Cl<−10‰. The δ 37Cl–TCPMe data thus supports the hypothesis that TCPMe is produced as a byproduct during DDT synthesis and is released to the environment through the same pathways as DDT. It is also consistent with tris-(4-chlorophenyl)methanol as the primary biotransformation product of TCPMe. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 08832927
- Volume :
- 25
- Issue :
- 9
- Database :
- Academic Search Index
- Journal :
- Applied Geochemistry
- Publication Type :
- Academic Journal
- Accession number :
- 52937332
- Full Text :
- https://doi.org/10.1016/j.apgeochem.2010.06.001