Stabilizing effect of extractives on the photo-oxidation of Acacia confusa wood

Abstract: This study shows the photo-stabilizing effect of extractives on wood. XPS and FTIR techniques were used to analyze the variations in chemical characteristics on the surfaces of non-extracted and extracted Acacia confusa heartwood after lightfastness test. XPS survey analyses reveal that non-extracted heartwood exhibits a higher O/C ratio than the extracted wood. Furthermore, results from the detailed analysis of C1s indicated that the photo-oxidative derivatives increased in both extracted and non-extracted specimens after lightfastness test. On extracted wood, the derivatives are mainly derived from lignin, whereas extractives are the major component responsible for the generation of derivatives on non-extracted wood surface. After leaching test of UV-irradiated specimens, it was noted that the degradation products were readily removed by water. More water-soluble derivatives were leached out from the extracted wood, although higher lignin content was observed on the non-extracted wood surface. In conclusion, it is shown that photodegradation of A. confusa wood can be retarded by extractives oxidation. [ABSTRACT FROM AUTHOR]