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Temperature dependence of fluorescence for EuCl3 in LiCl–KCl eutectic melt

Authors :
Im, Hee-Jung
Kim, Tack-Jin
Song, Kyuseok
Source :
Talanta. Aug2010, Vol. 82 Issue 3, p1057-1062. 6p.
Publication Year :
2010

Abstract

Abstract: The fluorescence of EuCl3 in LiCl–KCl eutectic melt according to temperature changes was investigated, and the spontaneous partial reduction of Eu3+ to Eu2+ at high temperature was confirmed by the fluorescence results. The fluorescence decreases when the temperature increases, and this was examined in detail. The studies of fluorescence provided information regarding the chemical and physical behavior of europium ions in the molten salt according to the temperature changes. It is applicable for monitoring species and concentrations and estimating the approximate chemical structure of the ions in molten salts. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
00399140
Volume :
82
Issue :
3
Database :
Academic Search Index
Journal :
Talanta
Publication Type :
Academic Journal
Accession number :
52820075
Full Text :
https://doi.org/10.1016/j.talanta.2010.06.026