Coordination-driven self-assembly in a single pot

Abstract: New multinuclear discrete heteroleptic complexes have been synthesized by mixing Pd(II), 2,2′-bipyridine and N,N′-(1,2-phenylene)diisonicotinamide in a single pot as a new approach. A dimeric molecular rhombus and a trimer in equilibrium are obtained where the dimer is the major product. Similar equilibrium is also observed when classical method is employed for the synthesis. The equilibrium is shifted exclusively in favour of the dimer upon addition of benzene. The complexes are characterized by NMR and ESI-MS methods. Crystal structure of the benzene encapsulated rhombus is presented. [Copyright &y& Elsevier]